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14) and could easily be separated using chiral high-performance liquid chromatography (HPLC).

Photodriven molecular motors are able to convert light energy into directional motion and hold great promise as miniaturized powering units for future nanomachines.Thus, our new molecular motor system enables for the first time to power fast unidirectional rotation under ambient and non-damaging conditions, representing the next crucial step towards developing highly efficient nanomachines that work at materials and biocompatible conditions.Our new molecular motor is based on the hemithioindigo (HTI) chromophore that can be operated exclusively by visible light in both switching directions.HTI consists of a thioindigo and a stilbene fragment, which are connected via a central double bond.On irradiation, HTI undergoes efficient and reversible Z/E or E/Z photoisomerization.

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